Cycloaddition Reactions of Heterocumulenes reviews cycloaddition reactions, particularly on hetercocumulenes having "four-electron" bonds.

This book discusses the chemical relationship among the various classes of heterocumulenes, including their chemical reactivity which ranges from highly reactive species to nearly inert compounds. This text also investigates the nucleophilic reactions of ketenes and isocyanates with suitable substrates, and if possible, correlates available data with the reactivity of these species in cycloaddition reactions. This book also investigates the cycloaddition reactions of carbon suboxide and other aspects of its chemistry due to the presence of many other interrelated reactions. The synthetic organic chemist should also investigate the application of isocyanate reactions associated with the cumulative double bonds. This text investigates carbodiimides as useful reagents for peptide synthesis, and notes that the stability of carbodiimides increases significantly with sterical hindrance around the cumulative double bond system. This book discusses three compounds that have a central electrophilic carbon atom, namely, carbon dioxide, carbonyl sulfide, and carbon disulfide. The book also describes the cycloaddition reactions of sulfenes, of N-sulfinylamines, of N-sulfinylsulfonamides, and of sulfurdiimides.

This book can prove useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry.

Preface
Chapter I. General Introduction

I. Scope

II. Reactivity

III. Cycloaddition Reactions

IV. Physiochemical Data

References

Chapter II. Ketenes

I. Introduction

II. Homopolymerization

III. 1,2-Cycloaddition Reactions

IV. 1,3-Cycloaddition Reactions

V. 1,4-Cycloaddition Reactions

References

Chapter III. Carbon Suboxide

I. Introduction

II. Cycloaddition Reactions

III. Nucleophilic Reactions

IV. Photochemical Reactions

References

Chapter IV. Isocyanates

I. Introduction

II. Homopolymerization

III. 1,2-Cycloaddition Reactions

IV. 1,3-Cycloaddition Reactions

V. 1.4-Cycloaddition Reactions

References

Chapter V. Isothiocyanates

I. Introduction

II. 1,2-Cycloaddition Reactions

III. 1,3-Cycloaddition Reactions

IV. 1,4-Cycloaddition Reactions

References

Chapter VI. Carbodiimides

I. Introduction

II. Homopolymerization

III. 1,2-Cycloaddition Reactions

IV. 1,3-Cycloaddition Reactions

V. 1,4-Cycloaddition Reactions

References

Chapter VII. Carbon Dioxide, Carbonyl Sulfide, and Carbon Disulfide

I. Introduction

II. 1,2-Cycloaddition Reactions

III. 1,3-Cycloaddition Reactions

References

Chapter VIII. Sulfenes

I. Introduction

II. 1,2-Cycloaddition Reactions

III. 1,3-Cycloaddition Reactions

IV. 1,4-Cycloaddition Reactions

References

Chapter IX. N-Sulfinylamines, N-Sulfinylsulfonamides, and Sulfurdiimides

I. Introduction

II. 1,2-Cycloaddition Reactions

III. 1.3-Cycloaddition Reactions

IV. 1,4-Cycloaddition Reactions

V. Sulfurdiimide Reactions

References

Appendix

Text

References

Author Index

Subject Index