Die supramolekulare Chemie hat sich nicht nur zu einem sehr wichtigen Teilgebiet der Chemie entwickelt, sondern auch zu einem lebendigen Grenzbereich, der interdisziplinär von Chemikern, Biologen, Physikern und Materialwissenschaftlern erforscht wird. Auch wenn dieses bereits mit dem Nobelpreis ausgezeichnete Gebiet noch recht jung ist, weiß schon heute jeder Chemiestudent, was man unter molekularer Erkennung, Wirt-Gast-Chemie oder Selbstassoziation versteht.
Dieses erste Buch zur supramolekularen Organometallchemie kombiniert zwei der aktivsten Forschungsgebiete in der Chemie. Es bietet einen umfassenden und hochakutellen Überblick über supramolekulare Organometallverbindungen, wohlgeordnet nach dem Bindungstyp, der die organometallischen Einheiten zusammenhält. Viele Informationen zur Synthese, zu Strukturen und Eigenschaften machen das Buch zu einer nutzerfreundlichen, wertvollen und faszinierenden Zusammenstellung, die ein breites Spektrum an Details zu Organometallübermolekülen aus Hauptgruppen-, Übergangs- oder f-Element-Metalle sowie eine vielseitige Auswahl an Liganden liefert. Zahlreiche Strukturen illustrieren den Text und machen dieses Buch so zu einer leicht lesbaren und allumfassenden Informationsquelle.
Autorentext
Process Engineers, Materials Scientists, Chemists in Industry, Electrochemists, Chemical Engineers, Power Engineers, Patent Lawyers
Klappentext
Ionel Haiduc, Frank T. Edelmann Supramolecular Organometallic Chemistry with a Foreword by Jean-Marie Lehn Supramolecular chemistry has become not only a major field of chemistry, but also a vivid interface between chemistry, biology, physics, and materials science. Although still a relatively young field of research, termini such as molecular recognition, host-guest chemistry, or self-assembly are now common knowledge even for chemistry students, and the research has already been honored with the Nobel prize. This first book on supramolecular organometallic chemistry combines two areas in chemistry that are experiencing the fastest developments. It provides a comprehensive, state-of-the-art review of various organometallic assemblies, and is arranged according to the types of intermolecular bonding. Details on the synthesis, structures, and properties of these compounds will be a valuable asset to the scientific community. The broad spectrum of assemblies containing main group element, transition metal, or f-element metal and a diverse range of ligands, held together by different bonding interactions make this a fascinating compilation. Illustrated extensively, this book is a very easy-to-read, all-you-need-to-know source of information.
Zusammenfassung
Supramolecular chemistry has become not only a major field of chemistry, but is also a vivid interface between chemistry, biology, physics, and materials science. Although still a relatively young field, termini such as molecular recognition, host-guest chemistry, or self-assembly are now common knowledge even for chemistry students, and research has already been honored with a Nobel Prize.
This first book on supramolecular organometallic chemistry combines two areas in chemistry that are experiencing the fastest developments. It provides a comprehensive review of various organometallic assemblies, arranged according to the types of intermolecular bonding. Details on the synthesis, structures, and properties of these compounds will be a valuable asset to the scientific community. The broad spectrum of assemblies containing main group element, transition metal, or f-element metal and a diverse range of ligands, held together by different bonding interactions make this a fascinating compilation. Illustrated extensively, this book is a very easily accessible, yet wide-ranging source of information.
Inhalt
BASIC CONCEPTS AND PRINCIPLES
Definitions
Intermolecular Bond Types on Organometallic Supramolecular Systems
References
MOLECULAR RECOGNITION AND HOST-GUEST INTERACTIONS
Organometallic Receptors and their Host-Guest Complexes
Organometallic Guests
References
SUPRAMOLECULAR SELF-ASSEMBLY THROUGH DATIVE BONDS (ELECTRON-PAIR DONOR-ACCEPTOR OR LEWIS ACID-BASE INTERACTIONS)
Group 12 Metals: Zinc, Cadmium, Mercury
Group 13 Metals: Aluminium, Gallium, Indium, Thallium
Group 14 Metals: Tin and Lead
References
SUPRAMOLECULAR SELF-ASSEMBLY THROUGH SECONDARY BONDS
Homoatomic Interactions
Group 12 Metals: Zinc, Cadmium, Mercury
Group 13 Metals: Gallium, Indium, Thallium
Group 14 Metals: Tin and Lead
Group 15 Metals: Arsenic, Antimony, Bismuth
Group 16 Metals: Selenium and Tellurium
References
SUPRAMOLECULAR SELF-ASSEMBLY THROUGH HYDROGEN BOND INTERACTIONS
Introduction
Group 14 Elements: Silicon, Germanium, Tin, Lead
Group 15 Elements: Arsenic, Antimony, Bismuth
Transition Metals (Organometallic Crystal Engineering)
References
SUPRAMOLECULAR SELF-ASSEMBLY THROUGH IONIC INTERACTIONS
Alkali Metals
Alkali Earth Metals
References
SUPRAMOLECULAR SELF-ASSEMBLY THROUGH PI-INTERACTIONS
Main Group Elements
Transition Elements
f-Elements
References