Equilibrium Constants of Liquid-Liquid Distribution Reactions, Part IV: Chelating Extractants is a compilation of liquid-liquid distribution equilibrium constants, with emphasis on extractants that form chelates. This tabulation includes all data published up to the end of 1972 for the major chelating extractants, and the given equilibrium parameters are supplemented by calculations (or recalculations) from experimental results.
This monograph consists of 12 chapters and characterizes the homogeneous equilibria involving the acid dissociation of the extractant in the aqueous phase and adduct or mixed ligand complex formation in the organic phase. The information given for each system includes the chemical reactions, the equilibrium constant, the temperature, and the composition of the aqueous and organic phases. Compounds covered include dialkyldithiocarbamic acids (such as diethyldithiocarbamic acid and dibutyldithioarbamic acid), tropolones (beta-isopropyltropolone and gamma-isopropyltropolone), N-acylhydroxylamines, N-nitroso-N-arylhydroxylamines (cupferrons), alpha-dioximes, diarylthiocarbazones (dithizones), 8-hydroxyquinolines, 8-mercaptoquinolines, o-dimercaptobenzenes (toluene-3,4-dithiol), beta-diketones (such as acetylacetone and hexafluoroacetylacetone), 4-acylpyrazol-5-ones, and o-nitrosophenols (1-nitroso-2-naphthol and 2-nitroso-1-naphthol).
This book will be of interest to chemists.
Inhalt
Preface
How to Use the Tables
I. Dialkyldithiocarbamic Acids
1-Pyrrolidinedithiocarbamic Acid
Diethyldithiocarbamic Acid
Dibutyldithioarbamic Acid
3-Phenyl-Pyrazolinedithiocarbamic Acid
5-Phenyl-Pyrazolinedithiocarbamic Acid
3-Phenyl-5-(2-Furyl)-Pyrazolinedithiocarbamicacid
3,5-Diphenyl-Pyrazolinedithiocarbamic Acid
II. Tropolones
Tropolone
ß-Isopropyltropolone
-Isopropyltropolone
III. N-Acylhydroxylamines
Benzohydroxamic Acid
N-Phenylacetylhydroxamic Acid
Caprinohydroxamic Acid
N-Furoyl-N-Phenylhydroxylamine
N-Benzoyl-N-Phenylhydroxylamine
N-Phenylacetyl-N-Phenylhydroxylamine
N-Cinnamoyl-N-Phenylhydroxylamine
N-(o-Trifluoromethyl-Benzoyl-N-Phenylhydroxylamine
N-(m-Trifluoromethyl)Benzoyl-N-Phenylhydroxylamine
N-(p-Trifluoromethyl)Benzoyl-N-Phenylhydroxylamine
N-(3-Trifluoromethyl-5-Nitro)Benzoyl-N-Phenylhydroxylamine
IV. N-Nitroso-N-Arylhydroxylamines (Cupferrons)
N-Nitroso-N-Naphthylhydroxylamine
N-Nitroso-N-Phenylhydroxylamine
V. a-Dioximes
Dimethylglyoxime
Ethylmethylglyoxime
1,2-Cyclohexanedionedioxime
1,2-Cycloheptanedionedioxime
a-Furildioxime
a-Benzildioxime
VI. Diarylthiocarbazones (Dithizones)
Diphenylthiocarbazone
Di-(p-Fluorophenyl)-Thiocarbazone
Di-(p-Chlorophenyl)-Thiocarbazone
Di-(o-Chlorophenyl)-Thiocarbazone
Di-(o-Bromophenyl)-Thiocarbazone
Di-(p-Bromophenyl)-Thiocarbazone
Di-(p-Iodophenyl)-Thiocarbazone
Di-(p-Methoxyphenyl)-Thiocarbazone
Di-(o-Tolyl)-Thiocarbazone
Di-(p-Tolyl)-Thiocarbazone
Di-(m-Trifluoromethylphenyl)-Thiocarbazone
Di-(2,4-Xylyl)-Thiocarbazone
Di-(a-Naphthyl)-Thiocarbazone
Di-(ß-Naphthyl)-Thiocarbazone
Di-(o-Diphenyl)-Thiocarbazone
VII. 8-Hydroxyquinolines
8-Hydroxyquinoline
5,7-Dichloro-8-Hydroxyquinoline
5,7-Dibromo-8-Hydroxyquinoline
5,7-Diiodo-8-Hydroxyquinoline
5-Chloro-7-Iodo-8-Hydroxyquinoline
2-Methyl-8-Hydroxyquinoline
4-Methyl-8-Hydroxyquinoline
5-Methyl-8-Hydroxyquinoline
5-Acetyl-8-Hydroxyquinoline
VIM. 8-Mercaptoquinolines
8-Mercaptoquinoline
5-Fluoro-8-Mercaptoquinoline
5-Chloro-8-Mercaptoquinoline
5-Bromo-8-Mercaptoquinoline
5-Iodo-8-Mercaptoquinoline
2-Methyl-8-Mercaptoquinoline
4-Methyl-8-Mercaptoquinoline
6-Methyl-8-Mercaptoquinoline
7-Methyl-8-Mercaptoquinoline
2,4-Dimethyl-8-Mercaptoquinoline
4,6-Dimethyl-8-Mercaptoquinoline
2-Phenyl-8-Mercaptoquinoline
IX. o-Dimercaptobenzenes
Toluene-3,4-Dithiol
X. ß-Diketones
Acetylacetone
Hexafluoroacetylacetone
Trifluoroacetylacetone
Dipropionylmethane
Heptafluorobutyryltrifluoroacetylmethane
Pivaloylacetylmethane
Isovaleroyltrifluoroacetone
2-Thenoylacetone
2-Furoyltrifluoroacetone
2-Thenoyltrifluoroacetone
Diisobutyrylmethane
Benzoylacetone
Benzoyltrifluoroacetone
Heptafluorobutyrylpivaloylmethane
Dipivaloylmethane
2-Naphthoyltrifluoroacetone
Dibenzoylmethane
2-Selenoyltrifluoroacetone
2-Selenoylacetone
2-Thenoyl-2-Selenoylmethane
2-Furoyl-2-Selenoylmethane
Di-2-Selenoylmethane
2-Selenoyl-2-Picolinylmethane
2-Selenoyl-Nicotinylmethane
2-Selenoyl-Isonicotinylmethane
Pyrroyltrifluoroacetone
2-Selenoyl-3-Nitrobenzoylmethane
Benzoyl-2-Selenoylmethane
XI. 4-Acylpyrazol-5-Ones
1-Phenyl-3-Methyl-4-Acetyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Trifluoroacetyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Trichloroacetyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Chloroacetyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Propionyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Ethoxycarbonyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Butyryl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Valeryl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Thenoyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Capronyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Benzoyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-p-Bromobenzoyl-Pyrazol-5-One
1-Phenyl-3-Methyl-4-Capryl-Pyrazol-5-One
XII. o-Nitrosophenols
1-Nitroso-2-Naphthol
2-Nitroso-1-Naphthol