Boron Oxide plays a key role in numerous glasses of high technological importance, yet its role in glass structure is far from clear. Indeed, in recent years there have been serious chal­ lenges to previous structure concepts for both crystalline and glassy borates. These challenges were sufficient to warrant a re­ examination of the structure of borate glasses using the most pow­ erful tools currently available. To provide a suitable forum for this undertaking, a four-day conference on "Boron in Glass and Glass Ceramics" was convened at Alfred University, June 3-8, 1977 to review the best scientific thinking on structure and to debate conflicting views and discuss properties and applications of borate glasses. This conference was also the first in a New University series on Glass Science to be rotated among Alfred University, The Pensyl vania State University, Rensselaer Polytechnic Institute, and the University of Missouri-Rolla. The present volume represents the proceedings of the first conference in this series. The volume begins with a review of the remarkable contribution of Jan Krogh-Moe to the understanding of the structure of Borate glasses. This review, authored by Professor N. J. Kreidl, concludes by dedicating the proceedings of this conference as a Krogh-Moe Fest­ schrift. The volume continues with a historical review by D. L. Griscom, originally prepared for circulation to the contributors prior to the conference. An Epilogue to the opening chapter brings the survey up-to-date in light of the conference papers.



Inhalt

A Dedication to Krogh-Moe: His Contribution to the Understanding of Borate Glasses.- Borate Glass Structure.- Epilogue.- Quantum Chemical Calculations to Model Borate Glass Electronic Structure and Properties.- Topological Considerations of Triangularly Connected Networks.- On the Fluctuation Structure of Vitreous Boron Oxide and Two-Component Alkali Borate Glasses.- Diffraction Analysis of Vitreous and Molten B2O3.- Laser-Induced Fluorescence Line Narrowing of Eu3+ in Lithium Borate Glass.- MSssbauer Investigation of the Incorporation of Tin and Iron in Sodium Borate Glasses.- Induced Silver Centers in Alkali Borate Glasses.- Structure of Borate and Borosilicate Glasses By Raman Spectroscopy.- Structure of Borate Glasses by Raman Spectroscopy.- Infrared Spectra and Structures of CVD B2O3-SiO2 Glasses.- The Vibrational Analysis of Boron in Vitreous Silica.- NMR Studies of Borates.- Structural Determinations for Sodium Borate Glasses Using B10 and B11 NMR.- Random Vector Statistical Studies of Amorphous Materials.- A Gas Probe Analysis of Structural Trends in Boron Glasses.- High-Temperature Borate Liquids: Physical Properties of Glass-Forming Compositions.- Kinetics of Volatilization of Sodium Borate Melts.- Viscous Flow in Binary Borate Melts.- Immiscibility and Microstructure in Amorphous Borates.- Crystal Growth Kinetics in Binary Borate Melts.- Viscoelastic Relaxation in B2O3.- Glass Formation in Borate Systems.- Electrical and Dielectric Properties of Borate Glasses.- Chemical Stability of Boron Containing Glass Enamels with Special Reference to Lead Release.- Chemical Durability of Borate Glasses.- Properties of Silica Glasses Containing Small Amounts of B2O3.- Optical Properties of the Sodium-Borate Glass System.- Effect of Water Content on Density, Refractive Index, and Transformation Temperature of Alkali Borate Glasses.- Acoustic Spectra of Glasses in the System Na2O-B2O3.- Industrial Borate Glasses.- Application of Borate Glasses and Various Boron Bearing Glasses to the Management of French Radioactive Wastes.- Application of Borate Glasses in Electronics.- Reaction Cured Borosilicate Glass Coating for Low-Density Fibrous Silica Insulation.

Titel
Borate Glasses
Untertitel
Structure, Properties, Applications
EAN
9781468433579
Format
E-Book (pdf)
Hersteller
Veröffentlichung
06.12.2012
Digitaler Kopierschutz
Wasserzeichen
Dateigrösse
45.84 MB
Anzahl Seiten
648