Paper Chromatography: A Laboratory Manual focuses on methods, technologies, and processes, and aims to provide readers with a readily accessible source for the uses and adaptations of paper chromatography.
The book first offers information on general methods, including descending, ascending, and ascending-descending chromatography, filter paper ""chromatopile"", ""reversed phase"" paper chromatography, and paper electrophoresis. The text then elaborates on quantitative methods and amino acids, amines, and proteins. Discussions focus on visual comparison, elution, area of spot, total color of spot, maximum color density, identification of amines, separation of proteins, and general directions.
The publication examines carbohydrates and aliphatic acids and steroids. Topics include simple sugars, miscellaneous derived sugars, and aliphatic acids. The text also ponders on purines, pyrimidines, and related substances and phenols, aromatic acids, and porphyrins.
The text is a valuable reference for readers interested in paper chromatography.



Inhalt

Foreword

I. Introduction


II. Theory


III. General Methods


Method I: Kapillaranalyse


Method II: Descending Chromatography


Trough


Chromatograph Chamber


Experimental Procedure


Method III: Ascending Chromatography


Chromatograph Chamber


Filter Paper Rack


Experimental Procedure


Comments


Method IV: Ascending Descending Chromatography


Chromatograph Chamber


Comments


Method V: Filter Paper "Chromatophile"


Method VI: "Reversed Phase" Paper Chromatography


Method VII: Circular Filter Paper Chromatography


Apparatus


Experimental Procedure


Identification of Zones


Method VIII: Microbiological and Enzymatic Methods


Method IX: Paper Electrophoresis


Paper Chromatography in an Electrical Field


Paper Electrophoresis


Experimental Technique


Effects of Temperature and Saturation on Paper Chromatograms


Filter Paper


Application of Sample to Paper


Micropipettes


Application of Sample


Elution of Spots


Photoelectric Apparatus


Densitometers


Ultraviolet Spectrophotometer


IV. Quantitative Methods


Method I: Visual Comparison


Visual Comparison Method after Berry and Cain


Method II: Elution


Elution Technique after Fowden, Boissonas, and Block


Method III: Area of Spot


Comment


Method IV: Total Color of Spot


Total Color Density Modified from Block and Bull


Total Color Density According to Rockland


Comment


Method V: Maximum Color Density


Maximum Color Density on Two-Dimensional Paper Chromatograms


Maximum Color Density on One-Dimensional Paper Chromatograms


Method VI: Area Density Method


Method VII: Retention Analysis


V. Amino Acids, Amines and Proteins


Section I: Amino Acids and Peptides


General Directions


Section II: Identification of Dinitrophenyl Amino Acids and Amino Alcohols


Dinitrophenyl Derivatives


Amino Alcohols


Section III: Identification of Amines


?? LEVELLING


Solvents


Paper


Quantities Used


Color Reagents


Preparation of Sample


Comments


Section IV: Separation of Proteins


Conventional Chromatography


Paper Electrophoresis


VI. Carbohydrates


Section I: Simple Sugars


General Directions


Experimental Procedure


Section II: Di- and Polysaccharides, Starch and Cellulose


Preparation of Samples


Detection of Spots


Section III: Substituted Sugars


General Directions


Section IV: Miscellaneous Derived Sugars


Sugar Acids


Polyhydric Alcohols


VII. Aliphatic Acids and Steroids


Section I: Aliphatic Acids


General Directions


Detailed Experiment


Section II: a-Keto Acids


General Directions for a-Keto Acids


Section III: Steroids


General Directions


Detailed Experiment


VIII. Purines, Pyrimidines, and Related Substances


General Directions


Quantities Used


Paper


Solvents


Techniques Used


Preparation of Samples


Detection and Quantitative Evaluation of Spots


IX. Phenols, Aromatic Acids, and Porphyrins


Section I: Phenols and Aromatic Acids


General Directions


Detailed Experiments


Section II: Porphyrins


General Directions


Detailed Experiment


X. Miscellaneous Organic Substances


Experimental Details


Adrenaline and Related Compounds


Lignin Degradation Products


Choline, Ethanolamine and Serine


Alkaloids


Nicotinic Acid and Related Compounds


ß-Indole Acetic Acid and Tryptophan


Anthraquinone Pigments


pH Indicators


Flavonoid Pigments


Chlorinated Organic Insecticides


Pterins


Urea, Creatine, Creatinine, and Miscellaneous Compounds


XI. Antibiotics and Vitamins


Section I: Antibiotics


General Directions


Detailed Experiments


Section II: Vitamins


General Directions


Experimental Details


XII. Inorganic Separations


General Directions


Quantities Used


Paper


Solvents


Special Techniques Used


Preparation of Samples


Detection and Determination


Experimental Details


Comments


Bibliography


Author Index


Subject Index



Titel
Paper Chromatography
Untertitel
A Laboratory Manual
EAN
9781483276878
Format
E-Book (pdf)
Veröffentlichung
03.09.2013
Digitaler Kopierschutz
Adobe-DRM
Dateigrösse
22.72 MB
Anzahl Seiten
205