Gas Solubilities: Widespread Applications discusses several topics concerning the various applications of gas solubilities.
The first chapter of the book reviews Henr's law, while the second chapter covers the effect of temperature on gas solubility. The third chapter discusses the various gases used by Horiuti, and the following chapters evaluate the data on sulfur dioxide, chlorine data, and solubility data for hydrogen sulfide. Chapter 7 concerns itself with solubility of radon, thoron, and actinon. Chapter 8 tackles the solubilities of diborane and the gaseous hydrides of groups IV, V, and VI of the periodic table. Chapter 9 discusses the solubility of gases containing fluorine, while Chapter 10 talks about Hildebrand's theory in the light of all gas solubility data. Chapter 11 covers the hydrogen halide system, while Chapter 12 deals with the solubility of gases in water and aqueous solutions of slats, inorganic acids and bases, and organic compounds. Chapter 13 discusses gases in sea water, while Chapter 14 covers aerosol propellants and Chapter 15 tackles the solubility of nitric oxide. Chapter 16 discusses the biotechnological aspects, and Chapter 17 talks about more on making holes. Chapter 18 covers the evaluation of data on phosphine.
The book would be of great interest to researchers and professionals concerned with applications of the soluble nature of gases.
Inhalt
1. What is Henry's Law
1.1. The Conventional Concept
1.2. Bunsen1s Heidelberg Group of 1855
1.3. Ostwald's Absorption Coefficient
1.4. Horiuti's Statements on the Ostwald Coefficient9
1.5. The Effect of the Vapor of Liquid S, the "Solvent"
1.6. Other Examples of Confusion
2. Effect of Temperature on Gas Solubility
2.1. The Concept of "Ideal Solubility"
2.2. Deviations from "Ideal Solubility"
2.3. The Reference Line (R-line) Procedure
2.4. n-Butane
2.5. Propane
2.6. Ethane
2.7. Methane
2.8. Data on Hydrogen, Ethane, Ethene, and Propane, Reported by Waters, Mortimer, and Clements (1970)
2.9· Data on Hydrogen and Deuterium, by Cook, Hansen, and Alder (1957)
2.10. Solubility of Hydrogen in Organic Liquids - Data by Maxted and Moon (1936)
2.11. Lannung's Data on Helium, Neon, and Argon (1930)
2.12. The Work of Siddkind and Kasarnowsky on the Solubility of Argon (1931,1933)
2.13. The Concept of Gas Solubility According to Phillips and Williams (1965)
2.14. The Solubility of Krypton - The Work of Korosy (1937), and van Liempt and van Wijk (1937)
2.15. Further Comments on the Making and Filling of Holes
2.16. R-line and "Ideal" Solubilities at 1 Atm and Different Temperatures
2.17. Data on the Noble Gases (He to Xe) by Clever, Battino, Saylor, and Gross
2.18. Solubility of Argon in Alcohols, Carbon Disulphide, and Perfluoroheptane: Lata by Gjaldbaek and Niemann (1958)
2.19. Hildebrand and Colleagues on Solubility and Entropy of Solution
2.20. The Theoretical Approach Based on Statistical Mechanics
2.21. Solubility of Helium, Neon, Hydrogen, and Deuterium in Liquid Argon
3. The Gases Used by Horiuti
3.1. Two Aspects: Solubility and Dilation
3.2. Solubility Data: Gases of "Great Solubility"
3.3. Solubility of Gases at "Medium Solubility"
3.4. Gases of "Small Solubility"
3.5. Data for N2O by Kunerth
3.6. Data on N2O by Yen and McKetta
3.7. Data by G. Jaldbaek for CO in Alcohols
4. Evaluation of Data on Sulfur Dioxide
4.1. The Two Dominating Conventional Concepts
4.2. The Muddle Over Henry's Law
4.3. The Solubility of Sulfur Dioxide in Diethylaniline
4.4. Solubility of SO2 in Benzene
4.5. Data by Albright, Shannon, Yu, and Chueh (1963)
4.6. Data by Pfeifer (1963)
4.7. Solubility in Di-n-butyl Ether
4.8. Solubility in Ethylene Glycol at 0°C
4.9. Solubility in Water
5. Evaluation of Chlorine Data
5.1. Principles and Methods of Measurements
5.2. The Technique of Taylor and Hildebrand (1923)
5.3. Solubility in Hydrocarbons
5.4. Solubility in Halogenated Hydrocarbons
5.5. Solubility in Carbon Disulfide and its Chlorination Products
5.6. Solubility in Organic Compounds Containing Oxygen
5.7. Solubility in Inorganic Chlorides
5.8. Solubility in Water
6. Evaluation of Solubility Data for Hydrogen Sulfide
6.1. Rejection of Henry's Law
6.2. Solubility in Nonaqueous Liquids
6.3. Solubility in n-Decane
6.4. Data by Gerrard
6.5. Solubility in Water
7. The Solubility of Radon 226/86Rn, Thoron 220/86Rn, and Actinon 219/86Rn in Liquids
7.1. The Measurement of Solubility by Radioactivity
7.2. Expression of Solubility of Radon as the Ostwald Coefficient
7.3. The Work of Eva Ramstedt
7.4. The Work of Kofier
7.5. The Work of Nussbaum and Hursh
7.6. Solubility Data for Radon
7.7. Confusion in the Data Books
7.8. Rational Evaluation of Data for Radon
7.9. The Effect of Temperature and Pressure
7.10. Solubility in Biological Fluids
7.11. Solubility in Aqueous Solutions of Salts and Organic Compounds
7.12. Recent Contributions
7.13. The Solubility of Thoron and Actinon
8. Solubilities of Diborane, and the Gaseous Hydrides of Groups IV, V, And VI of the Periodic Table
8.1. The Purpose of this Analysis
8.2. The Chromatographic Procedure Followed
8.3. Significance of the Distribution Coefficient, K
8.4. Group VI Systems: H2S, H2Se, H2Se, H2Te
8.5. Hydrides of Group V: PH3, AsH3, SbH3
8.6. Hydrides of Group IV: CH4, SiH4, GeH4, SnH4
8.7. Diborane
8.8. Solubility Spectrum 199
8.9. Lack of Numerical Correlation between Ê and N^ Values 199
8.10. Heats of Solution 199
8.11. Influence of Carrier Gas
8.12. Conclusion
8.13. Data for Arsine by Corriez and Berton
9. Solubility of Gases Containing Fluorine
9.1. SF6, CF4, NF3
9.2. Solubility of Octafluoropropane, C3F8, Octafluorocyclobutane, Cyclo C4F8, Chlorotrifluoromethane, CClF3; and for Contrast, Propane and Cyclopropane
9.3 Data for Hexafluoroethane Compared with those for Ethane
9.4. Solubility of Gaseous Chlorofluorohydrocarbons Containing Hydrogen
9.5. Solubility of Freons in Lubricating Oils of Refrigeration Units
9.6. Solubility of CClF3 and CCl2 and CCl2 in Four Liquid Hydrocarbons, and in Tetrachloromethane
9.7. Solubility of Gases in Hexafluorobenzene and in Benzene
9.8. Solubility of Boron Trifluoroacetonitrile, CF3CN
9.9. Solubility of Boron Trifluoride
9.10. Solubility of "Inert Gases" in Human Lung Tissue
9.11. Reference Diagrams for Other Gases Containing Fluorine
10. Hildebrand's Theory in the Light of all Gas Solubility Data
10.1. The Significance of Heat of Vaporization and Boiling Point/1 Atm
10.2. Hildebrand1s Regular Solutions
10.3. Hildebrand's Solubility Parameter
10.4. Examples of Invalid Classifications and Terminology
10.5. Extrapolations of the Mole Fraction, NA, vs Temperature Plots to the Critical Temperature, TC, of the Liquid, S
10.6. Solubility of Vinyl Chloride
10.7. Environmental Significance of the Solubility of Hydrocarbons in Water and Aqueous Solutions of Salts
10.8. Significance of the Solubility of Mercury in Water
10.9. Solubility of Tetraethyllead in Water
10.10. Ideality vs Reality
11. The Hydrogen Halid…