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1 The Askey Scheme of Orthogonal Polynomials.- 2.1 Markov Processes.- 3 Birth and Death Processes, Random Walks, and Orthogonal Polynomials.- 4 Sheffer Systems.- 5 Orthogonal Polynomials in Stochastic Integration Theory.- Stein Approximation and Orthogonal Polynomials.- Conclusion.- A Distributions.- B Tables of Classical Orthogonal Polynomials.- B.1 Hermite Polynomials and the Normal Distribution.- B.2 Scaled Hermite Polynomials and the Standard Normal Distribution.- B.3 Hermite Polynomials with Parameter and the Normal Distribution.- B.4 Charlier Polynomials and the Poisson Distribution.- B.5 Laguerre Polynomials and the Gamma Distribution.- B.6 Meixner Polynomials and the Pascal Distribution.- B.7 Krawtchouk Polynomials and the Binomial Distribution.- B.8 Jacobi Polynomials and the Beta Kernel.- B.9 Hahn Polynomials and the Hypergeometric Distribution.- C Table of Duality Relations Between Classical Orthogonal Polynomials.- D Tables of Sheffer Systems.- D.1 Sheffer Polynomials and Their Generating Functions.- D.2 Sheffer Polynomials and Their Associated Distributions.- D.3 Martingale Relations with Sheffer Polynomials.- E Tables of Limit Relations Between Orthogonal Polynomials in the Askey Scheme.- References.