The Production of Olefin-Containing and Fuel Gases reviews the production processes of gasification of distillate and residual liquid fuels employed in France, Germany, UK, USA, and Russia.
The monograph first offers information on the methods of chemical treatment of gases and products from the pyrolysis of crude oil and raw materials for the process of gasification. Discussions focus on the production of raw materials for oil-chemical synthesis and production of oil-chemical products.
The text then ponders on the theoretical presentation of high temperature pyrolysis of hydrocarbons and pyrolysis of hydrocarbon stock and resins. Topics include thermodynamic representation and mechanism of high temperature pyrolysis of hydrocarbons; methods for the calculation of the composition of a gas at equilibrium conditions; and dynamics of the change in composition of the reaction products in the gasification process.
The publication takes a look at contemporary installations for the gasification of liquid fuels, including the process of autothermic pyrolysis of hydrocarbons with air or steam-air blast and the processes of autothermic pyrolysis of crude petroleum in the presence of a catalyst.
The monograph is a dependable reference for chemical engineering students and plant engineers.
Inhalt
Preface
Introduction
Chapter I. Methods of Chemical Treatment of Gases and Products from the Pyrolysis of Crude Oil
The Production of Raw Materials for Oil-Chemical Synthesis
Hydrocarbon Gases and Hydrogen
Aromatic Hydrocarbons (Benzene, Toluene, Xylene)
Production of Oil-Chemical Products
The Production of Chlorine Derivatives
Alkylation of Benzene, its Homologues and the Chemical Treatment of Benzene Homologues
Synthetic Cleansing Materials (Detergents)
The Production of Plastics and Synthetic Rubber from Crude Oil
Manufacture of Alcohols from Crude Oils
The production of Sulfur, Sulphuric Acid and Ammonia from Crude Oil
Synthetic Ammonia
References
Chapter II. Raw Materials for the Process of Gasification
References
Chapter III. A Theoretical Presentation of the High Temperature Pyrolysis of Hydrocarbons
The Thermodynamic Representation and Mechanism of High Temperature Pyrolysis of Hydrocarbons
Calculation of the Rate of the Chemical Reactions of Continuous Flow Cracking
Methods for the Calculation of the Composition of a Gas at Equilibrium Conditions
References
Chapter IV. The Pyrolysis of Hydrocarbon Stock and Resins
Pyrolysis of Light Stock (Ethane, Propane, Butane and Gaseous Benzene)
Pyrolysis of Petroleum Distillate Fractions (Gas Oils)
The dynamics of the Change in Composition of the Reaction Products in the Gasification Process
Gasification of a n-Cetane Fraction
Gasification of a-Methyldecalin
Gasification of a 200-300°C Gas Oil Fraction
Gasification of Fuel Oils and Cracking-Residues
Pyrolysis of Shale Oil
Comparative Data Concerning the Pyrolysis of Petroleum and Shale Stocks
References
Chapter V. Contemporary Installations for the Gasification of Liquid Fuels
Gasification Installations for the Production of Illuminating and Power Gases
Processes for the Non-Catalytic Gasification of Crude Petroleum
The Pacific Coast Process
The Jones Process
The Hall Process
The Hall Process with Twin Generator
The Process of Autothermic Pyrolysis of Hydrocarbons with Air or Steam-Air Blast
Installations for the Autothermic Pyrolysis of Light Hydrocarbons
The Dayton-Faber Process
The Koppers-Hasche Process
The GEIM Process
The Otto Company Process
The Processes of Catalytic Gasification
The Processes of Autothermic Pyrolysis of Crude Petroleum in the Presence of a Catalyst
The SEGAS Process
The ONIA-GEGI Process
The ONIA-GEGI-DEMAG Process (Germany)
Gasification Installations for the Preparation of Hydrogen
The Texaco Process
The Iron-Steam Method
The Otto Process
Installations for the Production of Synthesis Gas
The Hercules Powder Process
Operating Conditions
The ONIA Process
The Standard Oil Process
The Carburation of Water Gas by Gases Obtained from Fuel Oils
Gasification Installations for the Production of Olefine-Containing Gases (Ethylene, Propylene)
The Catarole Process
The Hall Process
The Semi-Continuous Process in Tubular Reactors
The cyclic Process (ONIA-GEGI)
The Thermofor Process
The Ruhrgas Process
The Process of Contact Pyrolysis of Petroleum Residues
References
Index